三(二硫代草酸根)合二铁(II,III)酸四正丙基铵

三(二硫代草酸根)合二铁(II,III)酸四正丙基铵
识别
CAS号	293315-03-4
性质
化学式	C18H28Fe2NO6S6
摩尔质量	658.5 g·mol−1
外观	黑色针状晶体
密度	1.595 g·cm−3（88 K）; 1.555 g·cm−3（296 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三(二硫代草酸根)合二铁(II,III)酸四正丙基铵是一种配位化合物,化学式为[(ⁿC₃H₇)₄N][Fe^IIFe^III(dto)₃]，其中dto为二硫代草酸根（C₂O₂S₂²⁻）。它可由KBa[Fe^III(dto)₃]·3H₂O、FeCl₂·4H₂O和(C₃H₇)₄NBr在抗坏血酸的存在下于甲醇-水（10:3）溶液中通过扩散法反应得到。^[1]^[2]它在120 K和7 K分别发生电荷转移相变与铁磁相变。^[3]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 Miho Itoi, Atsushi Okazawa, Jun-ichi Yamaura, Sachiko Maki, Tokutaro Komatsu, Isabelle Maurin, Epiphane Codjovi, Kamel Boukheddaden, Norimichi Kojima. Structural Insight into Order–Disorder Transition and Charge-Transfer Phase Transition in an Iron Mixed-Valence Complex (n-C 3 H 7 ) 4 N[Fe II Fe III (dto) 3 ] with a Two-Dimensional Honeycomb Network. Inorganic Chemistry. 2018-11-05, 57 (21): 13728–13738 [2021-08-11]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.8b02211 （英语）.
^ M. Itoi, A. Taira, M. Enomoto, N. Matsushita, N. Kojima, Y. Kobayashi, K. Asai, K. Koyama, T. Nakano, Y. Uwatoko, J. Yamaura. Crystal structure and structural transition caused by charge-transfer phase transition for iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dto=C2O2S2). Solid State Communications. 2004-05, 130 (6): 415–420 [2021-08-11]. doi:10.1016/j.ssc.2004.02.034. （原始内容存档于2020-02-15）（英语）.
^ Miho Itoi, M. Enomoto, N. Kojima. Ferromagnetism of iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dithiooxalato:dto=C2O2S2). Journal of Magnetism and Magnetic Materials. 2004-05,. 272-276: 1093–1094 [2021-08-11]. doi:10.1016/j.jmmm.2003.12.640. （原始内容存档于2018-07-01）（英语）.

[IC-1] 1.0 ^1.1 ^1.2 Miho Itoi, Atsushi Okazawa, Jun-ichi Yamaura, Sachiko Maki, Tokutaro Komatsu, Isabelle Maurin, Epiphane Codjovi, Kamel Boukheddaden, Norimichi Kojima. Structural Insight into Order–Disorder Transition and Charge-Transfer Phase Transition in an Iron Mixed-Valence Complex (n-C 3 H 7 ) 4 N[Fe II Fe III (dto) 3 ] with a Two-Dimensional Honeycomb Network. Inorganic Chemistry. 2018-11-05, 57 (21): 13728–13738 [2021-08-11]. ISSN 0020-1669. doi:10.1021/acs.inorgchem.8b02211 （英语）.

[2] M. Itoi, A. Taira, M. Enomoto, N. Matsushita, N. Kojima, Y. Kobayashi, K. Asai, K. Koyama, T. Nakano, Y. Uwatoko, J. Yamaura. Crystal structure and structural transition caused by charge-transfer phase transition for iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dto=C2O2S2). Solid State Communications. 2004-05, 130 (6): 415–420 [2021-08-11]. doi:10.1016/j.ssc.2004.02.034. （原始内容存档于2020-02-15）（英语）.

[3] Miho Itoi, M. Enomoto, N. Kojima. Ferromagnetism of iron mixed-valence complex (n-C3H7)4N[FeIIFeIII(dto)3] (dithiooxalato:dto=C2O2S2). Journal of Magnetism and Magnetic Materials. 2004-05,. 272-276: 1093–1094 [2021-08-11]. doi:10.1016/j.jmmm.2003.12.640. （原始内容存档于2018-07-01）（英语）.

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