二氯化钌

二氯化钌是一种无机化合物，化学式为RuCl₂。它可由金属钌和氯气在一氧化碳的存在下反应得到，^[1]或通过三氯化钌和氢气在铂黑和氯化氢的存在下于乙醇中反应得到：^[2]

{\mathsf {Ru+Cl_{2}\ \xrightarrow {CO} \ RuCl_{2}}}

{\mathsf {2RuCl_{3}+H_{2}\ \xrightarrow {Pt,HCl} \ 2RuCl_{2}+2HCl}}

它可以进一步被氢还原为单质钌。^[3]它可以和芳烃形成配合物。^[4]

参考文献[编辑]

^ Jas. Lewis Howe, James L. Howe, S. C. Ogburn. RUTHENIUM DICHLORIDE. Journal of the American Chemical Society. 1924-02, 46 (2): 335–342 [2021-09-26]. ISSN 0002-7863. doi:10.1021/ja01667a008 （英语）.
^ Gall, H.; Lehmann, G. The preparation of salts of bi-valent ruthenlum. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1926. 59B: 2856-2860. ISSN 0365-9488.
^ Reymond, J. P.; Fouilloux, P. Use of carbon fabrics as support for hydrogenation catalysts usable in polyphasic reactors. Studies in Surface Science and Catalysis, 2000. 130(B): 995-1000.
^ T. Arthur, T.A. Stephenson. Synthesis of triple halide-bridged arene complexes of ruthenium(II) and osmium(II). Journal of Organometallic Chemistry. 1981-03, 208 (3): 369–387 [2021-09-26]. doi:10.1016/S0022-328X(00)86722-4. （原始内容存档于2018-06-26）（英语）.