五唑化银

五唑化银
识别
CAS号	2408152-17-8
SMILES	[Ag+].N=1N=N[N-]N1;
性质
化学式	AgN5
摩尔质量	177.9 g·mol−1
外观	苍白色固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

五唑化银是一种无机化合物，化学式为AgN₅，它可由五唑化镁或五唑化钴和硝酸银反应制得。^[1]^[2]由于它对光照敏感，其晶体结构未能测得。计算表明它的空间群可能为P2₁/c。^[3]

反应[编辑]

五唑化银和氨水反应，可以得到对空气稳定的[Ag(NH₃)₂][Ag₃(N₅)₄]。^[1]它和四甲基碘化铵反应，可以得到四甲基五唑化铵；^[4]和三氯化六氨合钴(III)反应，可以得到三(五唑)化六氨合钴(III)。^[5]

（左图）五唑化银和氨水反应得到的[Ag(NH₃)₂][Ag₃(N₅)₄]晶体；（右图）以及它的三维框架拓扑结构。^[1]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 ^1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.
^ Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.
^ Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN₅ and AgN₆. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.
^ Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH₄⁺, NH₃OH⁺, N₂H₅⁺, C(NH₂)₃⁺, and N(CH₃)₄⁺. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.
^ Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.

[Sun-1] 1.0 ^1.1 ^1.2 ^1.3 Sun, Chengguo; Zhang, Chong; Jiang, Chao; Yang, Chen; Du, Yang; Zhao, Yue; Hu, Bingcheng; Zheng, Zhansheng; Christe, Karl O. Synthesis of AgN5 and its extended 3D energetic framework. Nature Communications (Springer Science and Business Media LLC). 2018-03-28, 9 (1). ISSN 2041-1723. doi:10.1038/s41467-018-03678-y.

[2] Wang, Xieyang; Dong, Zhen; Yang, Rui; Zhou, Shengren; Ye, Zhiwen. Syntheses and Characterization of two cyclo‐pentazolate salts. Zeitschrift für anorganische und allgemeine Chemie (Wiley). 2021-01-27, 647 (6): 681–685. ISSN 0044-2313. doi:10.1002/zaac.202000309.

[3] Williams, Ashley S.; Nguyen Cong, Kien; Gonzalez, Joseph M.; Oleynik, Ivan I. Crystal structure of silver pentazolates AgN₅ and AgN₆. Dalton Transactions (Royal Society of Chemistry (RSC)). 2021, 50 (44): 16364–16370. ISSN 1477-9226. doi:10.1039/d1dt02319e.

[4] Yang, Chen; Zhang, Chong; Zheng, Zhansheng; Jiang, Chao; Luo, Jun; Du, Yang; Hu, Bingcheng; Sun, Chengguo; Christe, Karl O. Synthesis and Characterization of cyclo-Pentazolate Salts of NH₄⁺, NH₃OH⁺, N₂H₅⁺, C(NH₂)₃⁺, and N(CH₃)₄⁺. Journal of the American Chemical Society (American Chemical Society (ACS)). 2018-11-05, 140 (48): 16488–16494. ISSN 0002-7863. doi:10.1021/jacs.8b05106.

[5] Xu, Yuangang; Zhou, Jianxin; Li, Dongxue; Wang, Pengcheng; Lin, Qiuhan; Lu, Ming. Hexaamminecobalt(III) Cation as Multiple Hydrogen Bond Donors: Synthesis, Characterization and Energetic Properties of cyclo-Pentazolate and Azide Based Complexes. Crystal Growth & Design (American Chemical Society (ACS)). 2022-12-27, 23 (2): 811–819. ISSN 1528-7483. doi:10.1021/acs.cgd.2c01066.

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