四环丙基甲烷

四环丙基甲烷
识别
CAS号	332104-93-5
PubChem	57417320
性质
化学式	C13H20
摩尔质量	176.3 g·mol−1
外观	无色液体
熔点	~−15 °C
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四环丙基甲烷是一种有机化合物，化学式为C₁₃H₂₀，它是甲烷的四个氢全部被环丙基取代的产物。它可以3,3-二环丙基丙烯酸乙酯为原料，经多步反应，得到二环丙基二乙烯基甲烷，再小心地和重氮甲烷、乙酸钯反应制得。^[1]它在溶液中以S₄时间平均（time-averaged）对称的构象存在。^[2]

参考文献[编辑]

^ ^1.0 ^1.1 ^1.2 Sergei I. Kozhushkov, Rafael R. Kostikov, Alexander P. Molchanov, Roland Boese, Jordi Benet-Buchholz, Peter R. Schreiner, Christopher Rinderspacher, Ion Ghiviriga, Armin de Meijere. Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry. Angewandte Chemie International Edition. 2001-01-05, 40 (1): 180–183 [2023-01-12]. doi:10.1002/1521-3773(20010105)40:13.0.CO;2-K （英语）.
^ J. Edgar Anderson, Armin de Meijere, Sergei I. Kozhushkov, Lodovico Lunazzi, Andrea Mazzanti. Conformational Dynamics of Tetraisopropylmethane and of Tetracyclopropylmethane 1. Journal of the American Chemical Society. 2002-06-01, 124 (23): 6706–6713 [2023-01-12]. ISSN 0002-7863. doi:10.1021/ja017526j. （原始内容存档于2023-01-12）（英语）.

[prep-1] 1.0 ^1.1 ^1.2 Sergei I. Kozhushkov, Rafael R. Kostikov, Alexander P. Molchanov, Roland Boese, Jordi Benet-Buchholz, Peter R. Schreiner, Christopher Rinderspacher, Ion Ghiviriga, Armin de Meijere. Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry. Angewandte Chemie International Edition. 2001-01-05, 40 (1): 180–183 [2023-01-12]. doi:10.1002/1521-3773(20010105)40:13.0.CO;2-K （英语）.

[2] J. Edgar Anderson, Armin de Meijere, Sergei I. Kozhushkov, Lodovico Lunazzi, Andrea Mazzanti. Conformational Dynamics of Tetraisopropylmethane and of Tetracyclopropylmethane 1. Journal of the American Chemical Society. 2002-06-01, 124 (23): 6706–6713 [2023-01-12]. ISSN 0002-7863. doi:10.1021/ja017526j. （原始内容存档于2023-01-12）（英语）.

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