磷化镱

磷化镱是一种无机化合物，化学式为YbP，它是镱的磷化物之一。

制备及反应[编辑]

镱和磷化氢在液氨中反应，生成Yb(PH₂)₂·5NH₃，它分解可以得到磷化镱：^[3]

Yb(PH₂)₂·5NH₃ → Yb(PH₂)₂ + 5 NH₃

2 Yb(PH₂)₂ → YbP + 2 PH₃ + H₂

它在550 °C分解：^[3]

3 YbP → Yb₃P₂ + P

它可溶于盐酸、硝酸和王水。^[2]

^ Adrian T. Rowley, Ivan P. Parkin. Convenient synthesis of lanthanide and mixed lanthanide phosphides by solid-state routes involving sodium phosphide. Journal of Materials Chemistry. 1993, 3 (7): 689 [2021-12-15]. ISSN 0959-9428. doi:10.1039/jm9930300689 （英语）.
^ ^2.0 ^2.1 Sinitsyna, E. D.; Vasil'eva, I. G.; Mironov, K. E. Chemical properties of cerium, praseodymium, and ytterbium monophosphides. Khim. Fosfidov Poluprov. Svoistvami, 1970. 71-75. CODEN 22JPAY.
^ ^3.0 ^3.1 Pytlewski, L. L.; Howell, J. K. Preparation of Europium and ytterbium phosphides in liquid ammonia. Chemical Communications (London) (Royal Society of Chemistry (RSC)). 1967, (24): 1280. ISSN 0009-241X. doi:10.1039/c19670001280.