3-硝基二苯甲烷

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维基百科，自由的百科全书
3-硝基二苯甲烷
识别
CAS号 5840-41-5  checkY
性质
化学式 C13H11NO2
摩尔质量 213.23 g·mol−1
沸点 164—166 °C（437—439 K）（3 torr）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

3-硝基二苯甲烷是一种有机化合物，化学式为C13H11NO2。它可由3-硝基苄溴和苯硼酸在碳酸钠和钯催化剂的存在下反应得到，[2]该偶联反应也可使用氯化苄和3-硝基苯硼酸为原料进行反应。[3]它可以被氯化亚锡还原为3-氨基二苯甲烷。[4]Ag/C纳米颗粒可以催化它和氧气的反应，产物为3-硝基二苯甲酮。[5]

参考文献[编辑]

  1. ^ Kim Huard, Hélène Lebel. N ‐Tosyloxycarbamates as Reagents in Rhodium‐Catalyzed CH Amination Reactions. Chemistry - A European Journal. 2008-07-07, 14 (20): 6222–6230 [2021-12-24]. doi:10.1002/chem.200702027 （英语）. 
  2. ^ Michael J. Burns, Ian J. S. Fairlamb, Anant R. Kapdi, Petr Sehnal, Richard J. K. Taylor. Simple Palladium(II) Precatalyst for Suzuki−Miyaura Couplings: Efficient Reactions of Benzylic, Aryl, Heteroaryl, and Vinyl Coupling Partners. Organic Letters. 2007-12-01, 9 (26): 5397–5400 [2021-12-24]. ISSN 1523-7060. doi:10.1021/ol702291r. （原始内容存档于2021-12-24） （英语）. 
  3. ^ Nicolas Henry, Cécile Enguehard-Gueiffier, Isabelle Thery, Alain Gueiffier. One-Pot Dual Substitutions of Bromobenzyl Chloride, 2-Chloromethyl-6-halogenoimidazo[1,2- a ]pyridine and -[1,2- b ]pyridazine by Suzuki-Miyaura Cross-Coupling Reactions. European Journal of Organic Chemistry. 2008-10, 2008 (28): 4824–4827 [2021-12-24]. doi:10.1002/ejoc.200800544 （英语）. 
  4. ^ Mark A. Dekeyser, David M. Borth, Richard C. Moore, Anupama Mishra. Quantitative structure-activity relationships in acaricidal 4H-1,3,4-oxadiazin-5(6H)-ones. Journal of Agricultural and Food Chemistry. 1991-02, 39 (2): 374–379 [2021-12-24]. ISSN 0021-8561. doi:10.1021/jf00002a030 （英语）. 
  5. ^ Shuangxi Guo, Qi Zhang, Hongbo Li, Huifang Guo, Wei He. Ag/C nanoparticles catalysed aerobic oxidation of diaryl and aryl(hetero) methylenes into ketones. Nano Research. 2017-09, 10 (9): 3261–3267 [2021-12-24]. ISSN 1998-0124. doi:10.1007/s12274-017-1676-2 （英语）. 
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