嘔吐石

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來自德國南部上普法爾茨市沃爾森多夫的螢石(嘔吐石)

嘔吐石(英語:Antozonite),曾被稱為臭螢石[1] ,是一種放射性螢石,最早於1841年在巴伐利亞Wölsendorf發現[2],並在1862年命名。[3]

它的特點是存在多種含包裹體[4]當晶體被破碎時,氟會釋放出來。據推測,包裹體產生的β粒子會不斷將氟化鈣分解成鈣和氟原子。氟原子結合產生二氟陰離子,並在缺陷處失去多餘電子後形成氟。[5][6]氟隨後與大氣中的氧氣蒸汽反應,產生臭氧(其特徵氣味,最初誤認為是稱為Antozone的假想物質,也是礦物名稱的由來)和氟化氫

參考資料[編輯]

  1. ^ Carbonatites and alkalic rocks of the Arkansas River area, Fremont County, Colorado. 2. Fetid gas from carbonatite and related rocks頁面存檔備份,存於互聯網檔案館), American Mineralogist, vol. 50, November–December 1965; E. Wm. Heinrich and Raymond J. Anderson
  2. ^ Some physical properties of naturally irradiated fluorite頁面存檔備份,存於互聯網檔案館), American Mineralogist, Robert Berman, 1956; "The material has been given the name antozonite, after the supposed evanescent gas, antozone. Earlier names were Stinkstein and Stinkfluss (Hausmann, 1847)"
  3. ^ American Journal of Science頁面存檔備份,存於互聯網檔案館), 1862
  4. ^ Study of the solid and gaseous inclusions in the fluorites from Wölsendorf (Bavaria, F.R. of Germany) and Margnac (Haute Vienne, France) by microprobe and mass spectrometry, by R. Vochten, E. Esmans and W. Vermeirsch, Chemical Geology, volume 20, 1977 doi:10.1016/0009-2541(77)90047-X
  5. ^ First Direct Evidence that Elemental Fluorine Occurs in Nature頁面存檔備份,存於互聯網檔案館), News Release, Technische Universität München, 5 July 2012
  6. ^ Fluorine Finally Found in Nature頁面存檔備份,存於互聯網檔案館), Chemistry World, Royal Society of Chemistry, 11 July, 2012

外部連結[編輯]